OPTIMISATION OF SOLID PHASE MICROEXTRACTION (SPME) CONDITIONS FOR HEADSPACE ANALYSIS OF ORGANOPHOSPHATE PESTICIDES
Headspace vials (4.0 ml amber, screw top) with septum caps (PTFE/silicone septa) were heated and agitated with a Corning hot plate stirrer. SPME sampling stands (holding 8 vials) and magnetic stirrer (10 x 3 mm covered with PTFE) were used. A
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Supporting Information Qualitative and Quantitative Analysis of Volatile Constituents
Amber and clear headspace vials (20 mL) with screw caps were from MicroLiter Analytical Supplies, Inc. (Suwanee, GA, USA). Porapak Q sorbent (50/80 mesh) was from Supelco. An Alpha-2 pump from Ametek (Berwyn, PA, USA) was used for the dynamic A
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13 clear glass 20 mL headspace vials. Samples for GC×GC-TOFMS method 14 development and evaluation were prepared in equivalent amber glass vials to prevent 15 light degradation of alkyl-methoxypyrazines known to occur in Cabernet Sauvignon
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Tandem Mass Spectrometric Quantification of 93 Terpenoids in Cannabis Using Static Headspace
operation mode appear in Figure S1. For SHS-GC/MS/MS analysis, 5 mg of each of the extracts was accurately weighed in duplicates. All SHS samples were prepared in 20 mL amber rounded bottom HS vials sealed with a magnetic 32 mm PTFE septa cap by