21/5/2018 · HeadSpace Tailing. We have a Scion/Bruker GC456, with a HeadSpace autosampler SHS-40. The GC has a FID detector. We are injecting an OVIS STD. (We prepare it with Methanol, Ethanol, Acetone, IPA, Diethylamine, Ethyl Acetate, Triethylamine) The problem here, is that after a weekend the amines started tailing much more than before.