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15 Multidimensional Chromatography: Forensic and Toxicological Applications 15.1 Introduction 15.2 Liquid Chromatography–Gas Chromatography 15.3 Liquid Chromatography –Liquid Chromatography 15.4 Gas Chromatography–Gas Chromatography 15.5 On-Line Sample Preparation 15.6 Conclusions Acknowledgements References 407 407 408 410 414 427 429

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Chromatography of a perfume sample with headspace sampling. Figure 2. Movement of perfume molecules within a sealed and heated vial. much cleaner, easier and faster. A headspace sampling system automates this process by extracting a small volume of the headspace vapor from the vial and transferring it to the GC column.

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